Hello
Thanks for your question.
If you want to enforce MFA app usage you can leverage, Authentication policies here:
How To: Configure the multifactor authentication registration policy
Emergency access or break-glass accounts to prevent tenant-wide account lockout.
Service accounts and service principals, such as the Microsoft Entra Connect Sync Account.
Note that: this is a feature of Identity Protection which requires a P2 license
You can also configure an MFA registration Campaign instead to force users to sign up for the app, if you have only P1. See: https://zcusa.951200.xyz/en-us/entra/identity/authentication/how-to-mfa-registration-campaign
Also see:
Common Conditional Access policy: Require MFA for all users
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Regards,
Abiola