My best answer is that you are going to have to save the two floats in their on respective SQL DB table columns.
And you are going to have to have some kind of functional logic to combine them into Vector2.
Maybe you can make the EF model class be a partial class with the second partial class file having functions that are solely working with Vector2. EF would never see the functions as it does EF CRUD operations, but you would be able to call the functions to do Vector2 stuff.