@Arun Kumar KS Thanks for reaching out. You can refer to this document to get started on how to analyze service bus metrics. The available message metrics are listed here.
As per your requirement you need to create the alert on Count of dead-lettered messages in a Queue/Topic
metric and as per your requirement you can set the condition and evaluation.
Now you can perform what Actions you want to perform on this alert.
For more details on monitoring alerts, you can refer to this document. For creating alert, please refer to this document.
In case if you are looking to process the message when the message is received in dead letter queue then you can leverage the azure function service bus trigger or logic app workflows with service bus trigger.
Feel free to get back to me if you need any assistance.